FERROTSENNING p-DIKARBONIL HOSILALARI ASOSIDA BA’ZI BIR 3D METALLAR BILAN KOMPLEKS BIRIKMALAR SINTEZI VA OPTIK XOSSALARI
##plugins.themes.bootstrap3.article.main##
##article.abstract##
We obtained P-diketone, 1-ferrocenylbutanedione-1,3, by Claisen condensation. Ligands - hydrazones of monocarboxylic acids 1-ferrocenylbutanedione-1,3 (H L ) were synthesized by the interaction of carboxylic acid hydrazides with ferrocenoylacetone. The optical properties of all compounds synthesized in the work have been studied; based on the absorption spectra data, the values of the optical band gap were determined; it was shown that all the synthesized compounds are d-п type chromophores and have a band gap of 1.39-2.26 eV, i.e. they belong to narrow-gap semiconductors
##plugins.themes.bootstrap3.article.details##
Библиографические ссылки
Ileaney E.K., Logan S.R. Photochemical reactions of acetylferrocene // Inorganica Chimica Acta. - 1977. - V. 22. - P. 65 78.
Py F.F., Che D., Li G., Yao X.L., Zou D.P. Photo-induced ligand exchange reactions of ferrocenylacetylacetone in the presence of pyridine or4,4-dipyridyl: Crystal and molecular structure of trans-bis(ferrocenylacetylacetonato) dipyridineiron(II) // J. Organomet. Chem. - 1998. - V. 568. - P. l 65-169.
Cook, T.R., Zheng Y. R., Stang P. J. Metal-organic frameworks and self-assembled supramolecular coordination complexes: Comparing and contrasting the design, synthesis, and functionality of metal-organic materials // Chem. Rev. - 2013. - Vol. l 13. - №1. - P. 734-777.
Sulaymonova Z.A., Umarov B.B., Kodirova Z.K. Termicheskoye povedeniye meta-nitrobenzoilgidrazona ferrocenoilatsetona i ego kompleksa s ionom medi(II) // Universum: Chimiya I biologiya. Rossiya, - 2021. 11(89). - C. 15 19 URL: https://7universum.com/ru/nature/archive/new
Umarov B.B., Sulaymonova Z.A., Baxranova D.A. Sintez P-dikarbonilnix proizvodnix ferrotsena (Synthesis of Pdicarbonyl ferrocene derivates) // “Nauka i innovatsii v sovremennix usloviyax Uzbekistana” Respublikanskaya nauchnoprakticheskaya konferentsiya. Nukus - 2020, 20 may. - S. 114-115.