Synthesis and spectroscopic study of complex compounds of some 3D metals with the condensation product of 1-ferrocenylbutanedione-1,3 and succinic acid dihydrozide
##plugins.themes.bootstrap3.article.main##
Аннотация
We obtained by Claisen condensation b-diketone-1-ferrocenylbutanedione-1,3. The dicarboxylic acid dihydrazone of 1-ferrocenylbutanedione-1,3 (H4L) was synthesized by reacting succinic acid dihydrazide with ferrocenylacetone in a ratio of 2:1. Based on them, homobinuclear complex compounds with copper (II), zinc(II)and nickel(II) ions were obtained. The IR-, UV- and NMR spectra of the synthesized organic compounds were studied. The results of the studies showed that the H4L ligand in solution exists as a tau tomeric mixture: diketone (A), keto-enol (B) and in dienol(C) forms. According to the results of spectro scopic studies, the complexes were assigned a square planar structure, where the four times deprotonated ligand residue is coordinated by each metal atom through two oxygen atoms and a nitro gen atom of the hydrazone fragment. The fourth position in the planar square of the trans-N2O2 coordi nation site is occupied by the ammonia molecule. Planar five- and six-membered metal cycles of synthesizers are practically coplanar with each other.
##plugins.themes.bootstrap3.article.details##
Библиографические ссылки
T.J. Kealy, P.L. Pauson, A New Type of Organo-Iron Compound, Nature, 1951, Vol. 168, P. 1039-1940.
S.A. Miller, J.A. Tebboth, J.F. Tremaine, Dicyclopentadienyliron, J. Chem. Soc,195 2, Vol. 632, P. 632-635.
G. Wilkinson, F. Cotton, A.Cyclopentadienyl and Arene Metal Compounds, Progr. Inorg.Chem, 1959, Vol. 1, P. 1-124.
T.J. Colacot, A Concise Updateon the Applications of ChiralFerrocenylPhosphines in Homogeneous Catalysis Leading toOrganic
Synthesis, Chem. Rev., 2003., Vol. 103., P. 3101-3118.
Y. Ochi, M. Suzuki, T. Imaoka, M. Murata, H. Nishihara, Y. Einaga, K. Yamamoto, Controlled storage of ferrocene derivativesasredox-activemolecules in dendrimers, J Am Chem Soc, 2010, Vol. 132, P. 5061- 5069.
V.S. Sudhir, N.Y.P. Kumar, S. Chandrasekaran, Click chemistry inspired synthesis of ferrocene amino acids and other derivatives, Tetrahedron, 2010, Vol. 66, No. 6, P. 1327-1334.
F.F. Py, D. Che, G. Li, X.L. Yao, D.P. Zou, Photo-induced ligand exchange reactions of ferrocenylacetylacetone inthepresenceofpyridineor4,4-dipyridyl: Crystal and molecular structure of trans-bis(ferrocenylacetylacetonato) dipyridineiron(II), J. Organomet. Chem, 1998, V. 568, P. l 65-169.
Z.A. Sulaymonova, BB. Umarov, Preparation of ferrocenoylacetone metanitrobenzoylhydrazone and syntheses based on it, Chemical technology. Control and management, 2021, No. 4 (100), P. 5-11.
B.B. Umarov, Z.A. Sulaymonova, D.M. Tillaeva, Synthesis of ligands based on ferrocene derivatives with hydrazides of mono- and dicarboxylic acids, Universum: Chemistry and Biology. Russia, -2020. No. 3(69). S-19-22 URL: http://7universum.com/ru/nature/archive/item/8966.
B.B. Umarov, Z.A. Sulaymonova, M.K. Achylova, Synthesis of complexes based on ferrocene monocarbonyl derivatives with carboxylic acid hydrazides, Universum: Chem. Biol. 1–1 (79) (2021) 85–89.
B.B. Umarov, Z.A. Sulaymonova, D.M. Tillaeva, Complex compounds of transition metals based on the products of condensation of
ferrocenoylacetone with hydrazides of carboxylic acids, Bukhoro mukhandislik tekhnologiya institute ‘‘Development of science and
technology” Journal of Uzbekistan, 2020, No. 6.-P. 7-12.
A.A. Kazitsyna, N.B. Kupletskaya, Application of UV, IR and NMR spectroscopy in organic chemistry. M.: Book on Demand. -2013. – 264 p.
R. Silverstein, F. Webeter, D. Kiml, Spectrometric identification fication of organic compounds, M.: BINOM.knowledge laboratory (2011) - 520 p.
A.D. Antufeva, Synthesis and study of new conjugated ferro-censor structures D-A-D; and D-A(D”)-D’ type, Dis. Cand. Chem. Sci.. -Perm (2020) -155 p.
H. Meng, J. Zheng, A.J. Lovinger, B-C. Wang, P.G. Van Patten, Z. Bao, Oligofluorene-Thiophene Derivatives as High-Performance Semiconductors for Organic Thin Film Transistors, Chem. Mater, 2003, Vol. 15. –P. 1778–1787.
E.K. Ileaney, S.R. Logan, Photochemical reactions of acetylferrocene, Inorganica Chimica Acta, 1977, V. 22, P. 65-78.
N.N. Bukov, C.L. Kuznesova, T.V. Koctirina, Physical research methods: Electron spectroscopy, Krasnodar: KubSU, 2006. – 47 p.