THERMAL BEHAVIOR OF FERROCENOYLACETONE BENZOYLHYDRAZONE AND ITS COMPLEX WITH COPPER(II) ION

##plugins.themes.bootstrap3.article.main##

Zulfiya Qodirova

Аннотация

We obtained β-diketone-1-ferrocenibutanedione-1,3 (ferrocenoylacetone) by Claisen condensation. Hydrazone (H2L) of 1-ferrocenylbutanedione-1,3 benzoic acid was synthesized by the reaction of monocarboxylic acid hydrazide with ferrocenoylacetone. On its basis, a complex with a copper(II) ion was obtained.The thermal properties of the resulting ligand, ferrocenoylacetonebenzoylhydrazone and its complexCuL.NH3, were studied. From the obtained thermograms it is clearly seen that the most significant weight changes for the ligand - ferrocene derivative - benzoylhydrazoneferrocenoylacetone occur at Тd.max=260°С, when the mass loss rate reaches its maximum value, and for the CuL∙NH3 complex the similar temperature is - 180°C. The activation energies for the H2L ligand and its CuL∙NH3 complex were determined to be 36.32 kJ/mol and 5.367 kJ/mol, respectively.

##plugins.themes.bootstrap3.article.details##

Как цитировать
Qodirova, Z. (2024). THERMAL BEHAVIOR OF FERROCENOYLACETONE BENZOYLHYDRAZONE AND ITS COMPLEX WITH COPPER(II) ION. Центр Научных Публикаций (buxdu.Uz), 44(44). извлечено от http://journal.buxdu.uz/index.php/journals_buxdu/article/view/11487
Раздел
Статьи buxdu.uz

Библиографические ссылки

Patra M, Gasser G, Wenzel M, Merz K, Bandow JE, Metzler Nolte N. Synthesis and biological evaluation of ferrocene – containing bioorganometallics inspired by the antibiotic platensimycin lead structure // Organometallics . - 2010. - Vol. 29. - P. 4312-4315.

Morales-Espinoza E.G., Sanchez-Montes E., Klimova E., Klimova T., Lijanova I.V., Maldonado J.L., Ramos-Ortiz G, Hernandez-Ortega S., MartinezGarcia M. Dendrimers containing ferroceneandporphyrinmoieties: synthesis and cubic non-linear optical behavior // Molecules. - 2010. - №15. - P. 2564-2568.

Biot C., Glorian G., Maciejewski L.A., Brocard J.S. Synthesis and Antimalarial Activity in Vitro and in Vivo of a New Ferrocene-Chloroquine

Analogue // J. Med. Chem. -1997. -Vol. 40. - P. 3715-3718.

Osella D., Ferrali M., Zanello P., Laschi F., Fontani M., Nervid C., Cavigiolio C. On the mechanism of the antitumor activity of ferrocenium

derivatives //Inorg. Chim.Acta. - 2000. - Vol. 306. - P. 42-48.

Hudson R.D.A. Ferrocene polymers: current architectures, syntheses and utility // J Organomet Chem. -2001. - Vol. 637. - P. 47-50.

Zheng J, Wu KL, Shi TH, Xu Y. A series of novel ferrocene based dipeptide receptors for electrochemistry and biological activity // Appl

Organometal Chem. - 2013. - Vol. 27. - P. 698- 704.

Gupta S.R, Mourya P, Singh M.M, Singh V.P. Synthesis, structural, electrochemical and corrosion inhibition properties of two new ferrocene

Schif bases derived from hydrazides // J Organomet Chem. -2013. - Vol. 767. - P. 136- 140

Beer P.D., Smith D.R.J. Tunablebis (ferrocenyl) receptors forthe solution phase electrochemical sensing of transition-metal cations // J Chem Soc Dalton Trans. -1998. - Vol. 3. - P. 417-420.

Van Staveren D.R., Metzler-Nolte N. Bioorganometallic Chemistry of Ferrocene // Chem. Rev. - 2004. - Vol. 104. - № 12.- P. 5931-5985.

Dive D., Biot C. Ferrocene conjugates of chloroquineandotherantimalarials: the development of ferroquine, a new

antimalarial // Chem Med Chem. - 2008. - Vol. 3. - P. 4678-4682.

Top S., Vessieres A., Cabestaing C., Laios I., Leclereq G., Provot C., Jaouen G.,Ferrocifens and ferrocifenols as new potential weapons against breast cancer // J. Organomet. Chem. - 2018.- Vol. 3. - P. 637-639.

Top S., Vessieres A., Leclercq G., Quivy J., Tang J., Vaissermann J., Huche M., Jaouen G. Facile synthesis and strong antiproliferative activity of

disubstituteddiphenylmethylidenyl-[3]-ferrocenophanes on breast and prostate cancer cell lines // Chem. Eur. J. - 2003. - Vol. 9. - P.5223–5236.

Itoh T., Shirakami S., Ishida N., Yamashita Y., Yoshida T., Kim H-S., Wataya Y. Synthesis of novel ferrocenyl sugars and their antimalarial

activities // Bioorg Med ChemLett. - 2000. - Vol. 10. - P. 1657-1659.

Hussain R.A., Badshash A., Sohail M, Lal B., Altaf AA. Synthesis, chemical characterization, DNA interaction and antioxidant studies of

ortho, meta and parafluoro substituted ferrocene incorporated selenoureas. // InorgChimActa. - 2013. - Vol. 402. - P. 133-139.

Hassan A.S., Hafez T.S., Osman S.A., Ali M.M. Synthesis and in vitro cytotoxic activity of novel pyrazolo [1,5-a] pyrimidines and related

Schif bases // Turk J Chem. - 2015. - Vol. 83. - P. 27-39.

Abd-ElzaherМ.М., Mohamad M.E. Shakdofa, Hanan A. Mousa, Samia A. Moustafa. Synthesis, Characterization and Biological Activity of Some

Ferrocenyl Complexes Containing Antipyrine Moiety // SOP TRANSACTIONS ON APPLIED CHEMISTRY. -2014. -Vol. 1. -№1.- P. 42-52.

Abd-Elzaher M.M. Synthesis, characterization, and antimicrobial activity of cobalt(II), nickel(II), copper(II) and zinc(II) complexes with ferrocenyl Schiff bases containing a phenol moiety // Appl. Organomet. Chem. .-2004. -Vol. 18. - №4.- P. 149-155.

Ashraf S. Hassan, Taghrid S. Hafez. Antimicrobial Activities of Ferrocenyl Complexes // Journal of Applied Pharmaceutical Science. -2018. -Vol.

-№5.- P. 156-165. Availableonlineathttp://www.japsonline.com.

Deveci P, Arslanb U. Synthesis of novel ferrocene containing vic-dioxime ligands and their Ni(II), Cu(II) and Co(II) complexes: Spectral,

electrochemical and biological activity studies // J. Organomet Chem. - 2011. -Vol. 696. - P. 1756 -1763.

Ali S., Yasin G, Zuhra Z., Wu Z., Butler IS, Badshah A, Din IU. Ferrocene-based bioactive bimetallic thiourea complexes: synthesis and

spectroscopic studies // Bioinorganic Chemistry and Applications. - 2015. - Vol. 10. - №8. - P. 3756-3763.

Mahmood W.H, Mahmood N.F, Mohamed G.G. Synthesis, physiccochemical characterization, geometric structure and molecular

docking of new biologically active ferrocene based Schif base ligand with transition metal ions // ApplOrganometal Chem. -2017. - Vol. 848. - №8. - P. 288-301.

Chohan Z.H.Synthesis of organometallic-based biologically active compounds: In vitro antibacterial, antifungal and cytotoxic properties of some sulfonamide incorporated ferrocences//Journal of Enzyme Inhibition and Medicinal Chemistry. - 2009. - Vol. 29. - №1. - P. 169-175.

Умаров Б.Б., Сулаймонова З.А., Тиллаева Д.М. Комплексные соединения переходных металлов на основе конденсации производных

ферроцена с гидразидами карбоновых кислот. Научный вестник Наманганского государственного университета, 2020.- Выпуск: 9. - С. 58-63.

Умаров Б.Б., Сулаймонова З.А., Ачылова М.К. Синтез комплексов на основе монокарбонильных производных ферроцена с гидразидами карбоновых кислот // Universum: Химия и биология: электрон. Науч. Журн. - 2021.-№1(79).-С.85-91.URL:

(http://7universum.com/ru/nature/archive/item/category/179/).

Sulaymonova Z.A., Umarov B.B. Preparation of ferrocenoylacetone meta-nitrobenzoylhydrazone and syntheses based on it // Chemical technology. Control and management. - 2021. - No. 4 (100). - P. 5-11.

Наиболее читаемые статьи этого автора (авторов)

<< < 1 2 3 > >>